Anya: The power of the Wish made me a righteous sword to smite the unfaithful.
Xander: Well, hey! Good luck with that. Hope it works out for you.
Anya: You know, you can laugh, but I have witnessed a millenium of treachery and oppression from the males of the species and I have nothing but contempt for the whole libidinous lot of them.
Xander: Then why you talking to me?
Anya: I don’t have a date for the prom.
Xander: Well gosh. I wonder why not. It couldn’t possibly have anything to do with your sales pitch?
Anya: Men are evil. Will you go with me?
Xander: One of us is very confused, and I honestly don’t know which.
Buffy the Vampire Slayer — Season 3: Episode 20 — “The Prom”
The Love Pirate 
Anya was one of the best characters
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Definitely!
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Their Wedding or Joyce’s Death.. hard to pick a more heartwrenching moment
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Whew yeah, that’s a tough one, though if forced I’d probably go with Joyce.
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which Anya also stole that episode with her “explain to me”
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Yes, absolutely. That’s the scene/monologue that absolutely destroys me. It’s so unexpected and perfectly delivered.
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I love Anya and Xander 🙂
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